The Luche reduction is an organic reaction used to convert an α,β-unsaturated ketone to an allylic alcohol using cerium trichloride, sodium borohydride, and an alcohol solvent. The role of the cerium or other lanthanide metals is to coordinate to the alcohol, making its proton more acidic which allows for it to be abstracted by the carbonyl oxygen of the ketone starting material. The NaBH4 starting regent also reacts with the cerium activated alcohol to form a series of alkoxyborohydrides and these "hard reagents" result in the 1,2 hydride attack on the protonated carbonyl to give the final allylic alcohol product.
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